L-Phenylacetyl Carbinol

  • CasNo:53439-91-1
  • purity:99%
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Details

High quality purity >99% L-Phenylacetyl Carbinol 53439-91-1 for sale

  • Molecular Formula: C9H10O2
  • Molecular Weight: 150.177
  • Boiling Point: 253.3±20.0 °C(Predicted) 
  • PKA: 12.33±0.20(Predicted) 
  • PSA: 37.30000 
  • Density: 1.119±0.06 g/cm3(Predicted) 
  • LogP: 1.30900 

53439-91-1 Relevant articles

A One-Pot Two-Step Enzymatic Pathway for the Synthesis of Enantiomerically Enriched Vicinal Diols

Giovannini, Pier Paolo,Müller, Michel,Presini, Francesco,Baraldi, Serena,Ragno, Daniele,Di Carmine, Graziano,Jacoby, Christian,Bernacchia, Giovanni,Bortolini, Olga

, p. 973 - 978 (2021/02/01)

Enantiomerically enriched 1,2-diols are ...

Whole-Cell Biocatalysis in Seawater: New Halotolerant Yeast Strains for the Regio- and Stereoselectivity Reduction of 1-Phenylpropane-1,2-Dione in Saline-Rich Media

Andreu, Cecilia,del Olmo, Marcellí

, p. 1621 - 1628 (2020/03/05)

The application of green chemistry conce...

Synthesis of α-hydroxy ketones and vicinal (R, R)-diols by Bacillus clausii DSM 8716T butanediol dehydrogenase

Bongaerts, Johannes,Jablonski, Melanie,Kipp, Carina Ronja,Molinnus, Denise,Muschallik, Lukas,Pohl, Martina,Sch?ning, Michael J.,Selmer, Thorsten,Siegert, Petra,Wagner, Torsten

, p. 12206 - 12216 (2020/04/20)

α-hydroxy ketones (HK) and 1,2-diols are...

Immobilized chiral rhodium nanoparticles stabilized by chiral P-ligands as efficient catalysts for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione

Ruiz, Doris,M?ki-Arvela, P?ivi,Aho, Atte,Chiment?o, Ricardo,Claver, Carmen,Godard, Cyril,Fierro, José L.G.,Murzin, Dmitry Yu.

, (2019/08/26)

This work reports the efficient synthesi...

53439-91-1 Process route

methyl magnesium iodide
917-64-6

methyl magnesium iodide

(R)-2-phenyl-2-(trimethylsiloxy)acetonitrile
120443-82-5

(R)-2-phenyl-2-(trimethylsiloxy)acetonitrile

(R)-1-hydroxy-1-phenyl-2-propanone
1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

(S)-phenylacetylcarbinol
53439-91-1

(S)-phenylacetylcarbinol

Conditions
Conditions Yield
With hydrogenchloride; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) ether, reflux, 2 h;
With sulfuric acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) ether, reflux, 4 h; 2.) 0 deg C, 8 h;
1-phenyl-2-trimethylsiloxy-1-propene
43108-63-0

1-phenyl-2-trimethylsiloxy-1-propene

(R)-1-hydroxy-1-phenyl-2-propanone
1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

(S)-phenylacetylcarbinol
53439-91-1

(S)-phenylacetylcarbinol

Conditions
Conditions Yield
With (+)-(2S,8aS)-(camphorylsulfonyl)oxaziridine; methyllithium; Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) HMPA, THF, 0 deg C, 1h; 2.) -78 deg C;

53439-91-1 Upstream products

  • 917-64-6
    917-64-6

    methyl magnesium iodide

  • 120443-82-5
    120443-82-5

    (R)-2-phenyl-2-(trimethylsiloxy)acetonitrile

  • 43108-63-0
    43108-63-0

    1-phenyl-2-trimethylsiloxy-1-propene

  • 103-79-7
    103-79-7

    1-phenyl-acetone

53439-91-1 Downstream products

  • 405146-52-3
    405146-52-3

    (1S,2R)-2-((R)-2-Hydroxy-2-phenyl-ethoxyamino)-1-phenyl-propan-1-ol

  • 492-39-7
    492-39-7

    (1S,2S)-2-amino-1-phenylpropanol

  • 37577-28-9
    37577-28-9

    (1S,2R)-(+)-norphedrine

  • 100-52-7
    100-52-7

    benzaldehyde

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