L-Cysteine, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-, methyl ester

  • CasNo:233266-69-8
  • purity:99%
Inquiry Add to cart

Details

Factory Supply Industrial Grade L-Cysteine, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-, methyl ester 233266-69-8 with Best Price

  • Molecular Formula: C19H19NO4S
  • Molecular Weight: 357.43
  • Boiling Point: 548.9±50.0 °C(Predicted) 
  • PKA: 9.24±0.10(Predicted) 
  • PSA: 103.43000 
  • Density: 1.266±0.06 g/cm3(Predicted) 
  • LogP: 3.38740 

233266-69-8 Relevant articles

Expanding the scope of N → S acyl transfer in native peptide sequences

Cowper, Ben,Shariff, Leila,Chen, Wenjie,Gibson, Samantha M.,Di, Wei-Li,Macmillan, Derek

, p. 7469 - 7476 (2015)

Understanding the factors that influence...

Synthesis and cellular penetration properties of new phosphonium based cationic amphiphilic peptides

Silva Nigenda, Ezequiel,Postma, Tobias M.,Hezwani, Mohammed,Pirvan, Alin,Gannon, Susan,Smith, Carol-Anne,Riehle, Mathis,Liskamp, Rob M. J.

, p. 982 - 987 (2018)

A new category of phosphonium based cati...

Protein ubiquitination: Via dehydroalanine: Development and insights into the diastereoselective 1,4-addition step

Meledin, Roman,Mali, Sachitanand M.,Singh, Sumeet K.,Brik, Ashraf

, p. 4817 - 4823 (2016)

We report a strategy for site-specific p...

LIQUID COMPOSITIONS COMPRISING A LEVODOPA AMINO ACID CONJUGATE AND USES THEREOF

-

Page/Page column 74, (2021/03/13)

Disclosed herein are liquid pharmaceutic...

Visible-Light-Mediated S?H Bond Insertion Reactions of Diazoalkanes with Cysteine Residues in Batch and Flow

Chen, Lin,Cui, Yu-Sheng,Duan, Xiu,Guo, Kai,Qin, Long-Zhou,Qiu, Jiang-Kai,Sun, Qi,Yuan, Xin,Zhuang, Kai-Qiang

supporting information, p. 5093 - 5104 (2020/09/23)

We describe the application of S?H bond ...

Mild, Rapid, and Chemoselective Procedure for the Introduction of the 9-Phenyl-9-fluorenyl Protecting Group into Amines, Acids, Alcohols, Sulfonamides, Amides, and Thiols

Soley, Jacob,Taylor, Scott D.

, (2020/02/04)

The 9-phenyl-9-fluorenyl (PhF) group has...

Synthesis and NMR Characterization of the Prenylated Peptide, a-Factor

Bader, Taysir K.,Rappe, Todd M.,Veglia, Gianlugi,Distefano, Mark D.

, p. 207 - 238 (2019/01/04)

Protein and peptide prenylation is an es...

233266-69-8 Process route

Fmoc-Cys(Trt)-OMe
245088-56-6

Fmoc-Cys(Trt)-OMe

2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-mercaptopropionic acid methyl ester
233266-69-8

2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-mercaptopropionic acid methyl ester

Conditions
Conditions Yield
With chlorotriisopropylsilane; trifluoroacetic acid; In dichloromethane; at 20 ℃; for 4h;
98%
With triethylsilane; trifluoroacetic acid;
81%
With chlorotriisopropylsilane; trifluoroacetic acid; In dichloromethane; at 20 ℃; for 1h;
With chlorotriisopropylsilane; trifluoroacetic acid; In dichloromethane;
2.93 g
methanol
67-56-1

methanol

N<sup>α</sup>-fluoren-9-ylmethoxycarbonyl-L-cysteine
135248-89-4

Nα -fluoren-9-ylmethoxycarbonyl-L-cysteine

2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-mercaptopropionic acid methyl ester
233266-69-8

2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-mercaptopropionic acid methyl ester

Conditions
Conditions Yield
With hydrogenchloride; In water;
97%
With hydrogenchloride; In water; at 20 ℃;
75%
With hydrogenchloride; at 20 ℃;
75%
With hydrogenchloride; In water; at 25 ℃;
With hydrogenchloride; for 24h;
With oxalyl dichloride; at 0 - 20 ℃;

233266-69-8 Upstream products

  • 18595-34-1
    18595-34-1

    tert-butyl fluoroformate

  • 160978-34-7
    160978-34-7

    Nα -9-fluorenylmethyloxycarbonyl-S-allyloxycarbonylaminomethyl-L-cysteine methyl ester

  • 24424-99-5
    24424-99-5

    di-tert -butyl dicarbonate

  • 233266-72-3
    233266-72-3

    Nα -9-fluorenylmethoxycarbonyl-S-[N-[2,3,5,6-tetrafluoro-4-(N'-piperidino)phenyl]-N-(allyloxycarbonyl)aminomethyl]cysteine methyl ester

233266-69-8 Downstream products

  • 161639-16-3
    161639-16-3

    (R)-3-[5-tert-Butoxycarbonylamino-2-(2-methoxy-ethoxymethoxy)-benzyldisulfanyl]-2-(9H-fluoren-9-ylmethoxycarbonylamino)-propionic acid methyl ester

  • 161639-17-4
    161639-17-4

    (R)-3-[2-tert-Butoxycarbonylamino-5-(2-methoxy-ethoxymethoxy)-benzyldisulfanyl]-2-(9H-fluoren-9-ylmethoxycarbonylamino)-propionic acid methyl ester

  • 233266-72-3
    233266-72-3

    Nα -9-fluorenylmethoxycarbonyl-S-[N-[2,3,5,6-tetrafluoro-4-(N'-piperidino)phenyl]-N-(allyloxycarbonyl)aminomethyl]cysteine methyl ester

  • 75154-68-6
    75154-68-6

    methyl (2S)-N-tritylaziridine-2-carboxylate

Shopping Cart

Clear Inquiry